(4-{[(Pyridin-4-yl)methylidene]amino} phenyl)ferrocene
Abstract
The
asymetric
unit
of
compound,
[Fe(C5H5)(C17H13N2)], contains two independent molecules
whose conformations differ, especially in the 4-{(pyridin-4
yl)methylidene]amino}phenyl unit where one is flipped by
almost 180 . The cyclopentadienyl rings of the ferrocene unit
also exhibit different staggered conformations: in one mol
ecule the conformation is staggered by 9.43 (2) and in the
other by 24.46 (1) from an ideal eclipsed geometry. The plane
of the benzene ring is tilted away from the ferrocene group in
both molecules, with dihedral angles of 6.97 (1) and 10.30 (2) .
The benzene ring is also slightly twisted from the plane of the
pyridine ring, with dihedral angles of 5.98 (2) and 6.51 (2) in
the two molecules.
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