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    (4-{[(Pyridin-4-yl)methylidene]amino}- phenyl)ferrocene

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    Date
    2012-11-21
    Author
    Nyamori, V. O.
    Keru, Godfrey K.
    Omondi, B.
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    Abstract
    The asymetric unit of the title compound, [Fe(CH)(CHN)], contains two independent mol-ecules whose conformations differ, especially in the 4-{(pyridin-4-yl)methyl-idene]amino}-phenyl unit where one is flipped by almost 180°. The cyclo-penta-dienyl rings of the ferrocene unit also exhibit different staggered conformations: in one mol-ecule the conformation is staggered by 9.43 (2)° and in the other by 24.46 (1)° from an ideal eclipsed geometry. The plane of the benzene ring is tilted away from the ferrocene group in both mol-ecules, with dihedral angles of 6.97 (1) and 10.30 (2)°. The benzene ring is also slightly twisted from the plane of the pyridine ring, with dihedral angles of 5.98 (2) and 6.51 (2)° in the two mol-ecules.
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    https://www.researchgate.net/publication/235882800_4-Pyridin-4-ylmethyl-ideneamino-phen-ylferrocene
    https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588778/
    https://pubmed.ncbi.nlm.nih.gov/23468743/
    https://journals.iucr.org/e/issues/2012/12/00/hg5267/
    https://scite.ai/reports/4-pyridin-4-yl-methylidene]amino-phenyl-ferrocene-k2nyXy
    http://hdl.handle.net/123456789/4538
    https://doi.org/10.1107/S1600536812047812
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    • Journal Articles (PAS) [273]

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